TRIMETHYLSULFOXONIUM CHLORIDE CAS:5034-06-0

E avea le Trimethylsulfoxonium chloride ma se vailaʻau e tele ona aoga i le faʻaputuga o meaola, aemaise lava i le tali atu o le Swern oxidation mo le liua o ava malosi i aldehydes poʻo ketones. O lenei vailaʻau e galue o se vaega autu i le metotia o le Swern oxidation, faʻatasi ai ma le oxalyl chloride ma le dimethylsulfoxide, e mafai ai ona faʻaputuga lelei ma filifili lelei o ava malosi muamua ma lona lua i aldehydes ma ketones. O le faʻaaogaina o le trimethylsulfoxonium chloride i le faiga o le Swern oxidation e ofoina atu ai ni faʻamanuiaga e pei o tulaga tali faigofie, maualuga le fua, ma le fetaui ma le tele o vaega galue, ma avea ai ma meafaigaluega taua i le faʻaputuga o molelaʻau ola faigata. E le gata i lea, o le trimethylsulfoxonium chloride e maua le faʻaaogaina o se sui methylating i le kemisi ola, e mafai ai ona faʻaputuga le methylation o nucleophiles eseese i lalo o tulaga faigofie. E mafai e lenei vailaʻau ona faʻafaigofieina le faʻalauiloaina o vaega methyl i totonu o vailaʻau ola, e mafai ai ona faʻaputuga o oloa methylated eseese ma fausaga ma meatotino faʻapitoa. E le gata i lea, o le trimethylsulfoxonium chloride e faʻaaogaina i le sauniuniga o α-chloroketones ma α-bromoketones, o ni vailaʻau taua i le faʻaputuga o meaola mo nisi suiga ma le faʻatupuina. I le kemisi faʻafomaʻi ma le mauaina o vailaʻau, e mafai ona faʻaaogaina le trimethylsulfoxonium chloride i le faʻaputuga o vailaʻau faʻaputuga ma vailaʻau faʻaolaola. I le tuʻufaʻatasia o lenei vailaʻau i auala faʻaputuga, e mafai ai e le au suʻesuʻe ona maua le tele o vailaʻau eseese e iai gaioiga faʻafarmakoloki, e mafai ai ona suʻesuʻeina ni vailaʻau fou ma le atinaʻeina o vailaʻau fou. O le gafatia o le vailaʻau e suia ai fausaga molelaʻau ma faʻafaigofie ai tali taua faʻaolaola e fesoasoani i le mamanuina ma le faʻaleleia atili o molelaʻau ma aafiaga faʻaolaola e manaʻomia ma meatotino faʻamalolo. I le aotelega, o le trimethylsulfoxonium chloride e taua tele i le faʻaputuga o meaola, e ofoina atu ai i le au kemisi faʻaputuga se meafaigaluega taua mo suiga e pei o le oxidation, methylation, ma le faʻaaogaina o vaega faʻatino. O lona fetuʻunaʻiga, tulaga tali faigofie, ma le fetaui ma mea eseese e avea ai ma se vailaʻau taua i le pusa meafaigaluega a le au kemisi faʻaolaola ma le au suʻesuʻe o loʻo galulue i le mauaina o vailaʻau, kemisi faʻafomaʻi, ma le faʻaputuga o vailaʻau.